Relativistic Effects in Heavy-Element Chemistry and Physics (Wiley Series in Theoretical Chemistry)

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出版者:Wiley
作者:Hess, Bernd A. 編
出品人:
頁數:328
译者:
出版時間:2003-01-17
價格:USD 250.00
裝幀:Hardcover
isbn號碼:9780470841389
叢書系列:
圖書標籤:
  • Relativistic Chemistry
  • Heavy Element Chemistry
  • Theoretical Chemistry
  • Quantum Chemistry
  • Relativity
  • Nuclear Chemistry
  • Atomic Physics
  • Spectroscopy
  • Chemical Physics
  • Computational Chemistry
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具體描述

Heavy atoms and their compounds are important in many areas of modern technology. Their versatility in the reactions they undergo is the reason that they can be found in most homogeneous and heterogeneous catalysts. Their magnetism is the decisive property that qualifies them as materials for modern storage devices. The phenomena observed in compounds of heavy atoms such as phosphorescence, magnetism or the tendency for high valency in chemical reactions can to a large extent be traced back to relativistic effects in their electronic structure. Thus, in many aspects relativistic effects dominate the physics and chemistry of heavy atoms and their compounds. Chemists are usually aware of these phenomena, however, the theory behind them is not part of the standard chemistry curriculum and thus not widely known among experimentalists. Whilst the relativistic quantum theory of electronic structure is well established in physics, applications of the theory to chemical systems and materials have been feasible only in the last decade and their practical applications in connection with chemical experiment is somewhat out of sight of modern theoretical physics. Relativistic Effects in Heavy Element Chemistry and Physics intends to bridge the gap between chemistry and physics on the one hand and between theory and experiment on the other. Topics covered include: A broad range from quantum electrodynamics to the phenomenology of the compounds of heavy and superheavy elements A state-of-the-art survey of the most important theoretical developments and applications in the field of relativistic effects in heavy-element chemistry and physics in the last decade Special emphasis on the work of researchers in Europe and Germany in the framework of research programmes of the European Science Foundation and the German Science Foundation

本書以深入探討重元素化學與物理中的相對論效應為核心主題,係統地分析瞭高能粒子相互作用、核結構動力學以及相對論量子力學在不同化學和物理現象中的應用。這一書通過嚴謹的理論框架,解析瞭重元素反應機製中涉及相對論效應的細節,為研究人員提供瞭寶貴的參考視角。內容涵蓋從原子尺度到宏觀材料性能的多層次討論,特彆強調相對論效應在催化過程、核聚變和新興材料設計中的關鍵作用。 書中詳細闡述瞭相對論量子力學如何影響電子結構與化學反應路徑,通過對費曼積分、相對論狄拉剋方程及其應用的深入剖析,解釋高密度環境下元素行為的本質變化。同時,書籍係統介紹瞭相對論效應在光譜分析中的應用,如重元素的吸收與發射特徵,通過量子軌道理論揭示復雜分子體係中微弱信號的重要性。這些內容不僅幫助讀者理解高精度計算方法,還提供瞭實驗設計建議,適用於化學傢、物理學傢及材料科學研究人員。 書的結構設計注重邏輯性與可擴展性,從基礎概念入手,逐步深入到具體案例分析,內容豐富且貼近實際問題。特彆是在相對論效應如何影響離子化過程、反應速率和穩定態形成方麵,提供瞭詳盡的物理模型支持和實證數據。這種以理論與實驗緊密結閤的方法,使書籍成為探索高能現象在微觀尺度上的重要工具。 此外,作者結閤現代計算技術,如DFT與相對論修正的融閤,係統闡述瞭如何利用多尺度建模解決復雜化學問題。這些內容不僅拓展瞭讀者對理論物理的理解,也為實驗驗證提供瞭明確方嚮。書中還引用瞭大量最新研究成果和典型案例,確保信息的前沿性與實用性。 總體而言,這本書以其係統性、嚴謹性與豐富性,為讀者打開瞭解重元素相對論效應的新窗口,同時為實際研究提供瞭堅實的理論支撐和方法指導。無論是新手學者還是專業研究人員,都可從中獲取有價值的知識和啓發。

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